西南大学18春[1095]有机化学（二）在线作业资料
10951、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490012603773056774.png"title="201703201490012603773056774.png"alt="图片1.png"/>
辅导联系q761296021
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参考答案：<imgtitle="201706081496919533936013942.png"alt="图片2.png"src="/resourcefile/uploadFiles/file/questionImgs/201706081496919533936013942.png"width="97"height="71"style="width:97px;height:71px;"/>；<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490012824693090800.png"title="201703201490012824693090800.png"alt="1B.png"/>；
2、蛋白质的基本组成单位是（）。
氨基酸
脱氧核糖核酸
核糖核酸
葡萄糖
参考答案：氨基酸；
3、<imgtitle="201709041504501633937008967.png"alt="图片32.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504501633937008967.png"width="472"height="80"style="width:472px;height:80px;"/>
<imgtitle="201709041504501646224068036.png"alt="图片33.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504501646224068036.png"width="120"height="83"style="width:120px;height:83px;"/>
<imgtitle="201709041504501654682093043.png"alt="图片34.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504501654682093043.png"width="128"height="81"style="width:128px;height:81px;"/>
<imgtitle="201709041504501661744088506.png"alt="图片35.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504501661744088506.png"width="100"height="47"style="width:100px;height:47px;"/>
<imgtitle="201709041504501668297001936.png"alt="图片36.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504501668297001936.png"width="92"height="46"style="width:92px;height:46px;"/>
参考答案：<imgtitle="201709041504501668297001936.png"alt="图片36.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504501668297001936.png"width="92"height="46"style="width:92px;height:46px;"/>；
4、<imgtitle="201709041504509822787077787.png"alt="图片81.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504509822787077787.png"width="571"height="60"style="width:571px;height:60px;"/>
E.<imgtitle="201709041504509838236024542.png"alt="图片82.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504509838236024542.png"width="92"height="54"style="width:92px;height:54px;"/>
<imgtitle="201709041504509854829066998.png"alt="图片84.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504509854829066998.png"width="94"height="52"style="width:94px;height:52px;"/>
<imgtitle="201709041504509847519092972.png"alt="图片83.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504509847519092972.png"width="90"height="52"style="width:90px;height:52px;"/>
<imgtitle="201709041504509866767067176.png"alt="图片85.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504509866767067176.png"width="136"height="47"style="width:136px;height:47px;"/>
5、<imgtitle="201709041504536934279065349.png"alt="图片157.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504536934279065349.png"width="602"height="83"style="width:602px;height:83px;"/>
<imgtitle="201709041504536971237086343.png"alt="图片161.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504536971237086343.png"width="126"height="96"style="width:126px;height:96px;"/>
<imgtitle="201709041504536958961093249.png"alt="图片160.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504536958961093249.png"width="147"height="97"style="width:147px;height:97px;"/>
<imgtitle="201709041504536952474068140.png"alt="图片159.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504536952474068140.png"width="126"height="93"style="width:126px;height:93px;"/>
<imgtitle="201709041504536946062077743.png"alt="图片158.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504536946062077743.png"width="145"height="97"style="width:145px;height:97px;"/>
6、下列方法中，（）可以使糖的碳链增长。
佛尔递降法
芦福递降法
克利安尼氰化增碳法
碳二亚胺法
7、请对下列分子进行合理的切断，并写出其合成子（）<imgtitle="201709051504541718723069093.png"alt="图片167.png"src="/resourcefile/uploadFiles/file/questionImgs/201709051504541718723069093.png"/>
<imgtitle="201709051504542018616097520.png"alt="图片170.png"src="/resourcefile/uploadFiles/file/questionImgs/201709051504542018616097520.png"width="216"height="60"style="width:216px;height:60px;"/>
<imgtitle="201709051504542000806094873.png"alt="图片168.png"src="/resourcefile/uploadFiles/file/questionImgs/201709051504542000806094873.png"width="208"height="60"style="width:208px;height:60px;"/>
<imgtitle="201709051504542025988070238.png"alt="图片171.png"src="/resourcefile/uploadFiles/file/questionImgs/201709051504542025988070238.png"width="217"height="67"style="width:217px;height:67px;"/>
<imgtitle="201709051504542010154004187.png"alt="图片169.png"src="/resourcefile/uploadFiles/file/questionImgs/201709051504542010154004187.png"width="217"height="64"style="width:217px;height:64px;"/>
8、<imgtitle="201709041504504841152027159.png"alt="图片53.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504504841152027159.png"width="412"height="55"style="width:412px;height:55px;"/>
<imgtitle="201709041504504860651041379.png"alt="图片55.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504504860651041379.png"width="50"height="47"style="width:50px;height:47px;"/>
<imgtitle="201709041504504853577067979.png"alt="图片54.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504504853577067979.png"width="60"height="51"style="width:60px;height:51px;"/>
<imgtitle="201709041504504875929004206.png"alt="图片57.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504504875929004206.png"width="84"height="26"style="width:84px;height:26px;"/>
<imgtitle="201709041504504867526077551.png"alt="图片56.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504504867526077551.png"width="62"height="24"style="width:62px;height:24px;"/> 无忧答案网www.ap5u.com
9、写出对氨基苯乙酮的结构（）
<imgtitle="201709041504539166112031606.png"alt="图片163.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504539166112031606.png"width="83"height="90"style="width:83px;height:90px;"/>
<imgtitle="201709041504539190675001822.png"alt="图片166.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504539190675001822.png"width="143"height="87"style="width:143px;height:87px;"/>
<imgtitle="201709041504539175222097852.png"alt="图片164.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504539175222097852.png"width="104"height="97"style="width:104px;height:97px;"/>
<imgtitle="201709041504539182271015514.png"alt="图片165.png"src="/resourcefile/uploadFiles/file/questionImgs/201709041504539182271015514.png"width="128"height="96"style="width:128px;height:96px;"/>
10、胡萝卜素类化合物广泛地存在于植物和动物的脂肪内，属于___萜化合物。
二
单
三
四
11、下列氨基酸中，（）不属于必需氨基酸。
蛋氨酸
异亮氨酸
精氨酸
赖氨酸
12、下列基团中____不能用来保护羟基
THP（四氢吡喃基）
对甲氧基苄氧基甲基p-MeOC6H4CH2OCH2―简写为PMBM
硅保护基，例如三乙基硅基（TES）
苄基
13、下列反应中，（）不属于周环反应。
Cope重排
Claisen重排
Aldol缩合反应
Diels-Alder反应
14、<imgtitle="201709021504351977498025306.png"alt="图片89.png"src="/resourcefile/uploadFiles/file/questionImgs/201709021504351977498025306.png"width="391"height="91"style="width:391px;height:91px;"/>
<imgtitle="201709021504352020070071398.png"alt="图片93.png"src="/resourcefile/uploadFiles/file/questionImgs/201709021504352020070071398.png"width="73"height="84"style="width:73px;height:84px;"/>
<imgtitle="201709021504351988821094267.png"alt="图片90.png"src="/resourcefile/uploadFiles/file/questionImgs/201709021504351988821094267.png"width="84"height="86"style="width:84px;height:86px;"/>
<imgtitle="201709021504351999657081463.png"alt="图片91.png"src="/resourcefile/uploadFiles/file/questionImgs/201709021504351999657081463.png"width="84"height="86"style="width:84px;height:86px;"/>
<imgtitle="201709021504352009309030889.png"alt="图片92.png"src="/resourcefile/uploadFiles/file/questionImgs/201709021504352009309030889.png"width="52"height="117"style="width:52px;height:117px;"/>
15、芳香胺的碱性比氨强。
A.√
B.×
16、乳糖用酸水解，得一分子D一半乳糖和一分子D一葡萄糖酸。
A.√
B.×
17、氨基酸的熔点很高，多数氨基酸受热分解而不熔融。
A.√
B.×
18、胺很容易氧化，特別是芳香胺，大多数氧化剂使胺氧化成焦油状的复杂物质，但是过氧化氢、过酸能使三级胺氧化为氧化胺。
A.√
B.×
19、羧酸比酰卤、混合酸酐或活泼酯都活泼，因为一X，一OR(R中有吸电子基），一OCOOR，都是比一OH较好的离去基团。
A.√
B.×
20、Hinsberg反应可用于分离鉴别一级胺、二级胺和三级胺。
A.√
B.×
21、喹啉、异喹啉是三级胺，具有碱性。
A.√
B.×
22、Fehling试剂或Benedict试剂常与醛糖及酮糖反应产生氧化亚铜红色沉淀，这类糖称为还原糖。
A.√
B.×
23、氨具有棱锥形的结构，氮用sp3杂化轨道与三个氢的s轨道重叠，形成三个sp3-sσ键，成棱锥体。
A.√
B.×
24、<imgtitle="201708151502771055826020679.png"alt="图片9.png"src="/resourcefile/uploadFiles/file/questionImgs/201708151502771055826020679.png"width="362"height="93"style="width:362px;height:93px;"/>
A.√
B.×
25、吡咯的α-C、β-C和N上均能发生质子化反应。而实际上,N上的质子化是主要的。
A.√
B.×
26、氨具有平面的结构，氮用sp2杂化轨道与三个氢的s轨道重叠，形成三个sp2-sσ键，成平面结构。
A.√
B.×
27、卤代烷与氨或胺的反应，称为Hofmann烷基化反应，是制备纯净的一级胺的好方法。
A.√
B.×
28、凡是具有游离氨基的氨基酸水溶液和水合茚三酮反应时都能生成一种黄色的化合物，反应十分灵敏，是鉴定氨基酸最简便的方法。
A.√
B.×
29、<imgtitle="201708151502769488857076123.png"alt="图片4.png"src="/resourcefile/uploadFiles/file/questionImgs/201708151502769488857076123.png"width="360"height="64"style="width:360px;height:64px;"/>
A.√
B.×
30、苯炔是一个高度活泼的亲双烯体，能与大多数1,3-二烯类化合物发生Diels-Alder反应即双烯反应。
A.√
B.×
31、所有属于4n+2体系的共轭多烯在基态时的HOMO也都有相同的对称性，加热时必须采取对旋关环的方式。同样，它们在激发态时的HOMO也都有相同的对称性，所以光照时，必须采取顺旋关环的方式。
A.√
B.×
32、脯氨酸是碱性氨基酸。
A.√
B.×
33、苯并五元杂环的亲电取代反应主要在杂环的C-2位上发生。
A.√
B.×
34、萜类化合物可以看作是两个或两个以上的异戊二烯分子，以头尾相连的方式结合起来的。
A.√
B.×
35、氨基酸中的手性碳原子可以用R、S构型法标记，但与糖一样，更习惯用D或L构型法标记。天然的氨基酸多数是_____的。
36、在合成多肽时，一些侧链的基团需要保护起来，特别是巯基，很容易发生氧化还原反应，一般是用______将它保护起来。
37、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490019286423096474.png"title="201703201490019286423096474.png"alt="填图3.png"width="518"height="76"style="width:518px;height:76px;"/>
38、完成下列反应<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490019075408081199.png"title="201703201490019075408081199.png"alt="填图1.png"/>
39、完成下列反应<imgtitle="201703201490013204068091066.png"alt="3.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490013204068091066.png"/>
40、<imgtitle="201703201490014466233092341.png"alt="21.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490014466233092341.png"width="394"height="110"style="width:394px;height:110px;"/>
41、完成下列反应<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201706081496922898257016906.png"title="201706081496922898257016906.png"alt="图片6.png"width="391"height="80"style="width:391px;height:80px;"/>
42、<imgtitle="201703201490015787656014659.png"alt="21.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490015787656014659.png"/>
43、完成下列反应<imgtitle="201703201490017351702039727.png"alt="24.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490017351702039727.png"width="670"height="63"style="width:670px;height:63px;"/>
44、完成下列反应式：<imgtitle="201703201490017224353057548.png"alt="221.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490017224353057548.png"/>
45、完成下列反应<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490019332872039245.png"title="201703201490019332872039245.png"alt="填图4.png"width="478"height="73"style="width:478px;height:73px;"/>
46、完成下列反应<imgtitle="201703201490015903129069724.png"alt="23.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490015903129069724.png"/>
47、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490015306794042888.png"title="201703201490015306794042888.png"alt="填图1.png"/>
48、完成下列反应<imgtitle="201703201490013279360010906.png"alt="4.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490013279360010906.png"/>
49、蒎烯中有一个不稳定的四元环，很容易发生______，使碳架发生改变。
50、完成下列反应<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490017400021012886.png"title="201703201490017400021012886.png"alt="填图3.png"width="404"height="93"style="width:404px;height:93px;"/>
51、完成下列反应<imgtitle="201703201490013596565012770.png"alt="填空图片2.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490013596565012770.png"width="526"height="121"style="width:526px;height:121px;"/>
52、<imgtitle="201703201490014534554084455.png"alt="22.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490014534554084455.png"/>
53、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490013825180008662.png"title="201703201490013825180008662.png"alt="填空图片4.png"width="390"height="57"style="width:390px;height:57px;"/>
54、完成下列反应<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490017265860043844.png"title="201703201490017265860043844.png"alt="填图2.png"/>
55、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490017198427097434.png"title="201703201490017198427097434.png"alt="填图1.png"/>
56、Edman方法中，用______和N端的氨基反应，生成苯氨基硫代甲酸衍生物。
57、用于保护氨基的两个最重要的化合物是______和______。
58、____被认为是最小的一个蛋白质。
59、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490013713395058005.png"title="201703201490013713395058005.png"alt="填空图片3.png"width="546"height="67"style="width:546px;height:67px;"/>
60、D-葡萄糖及______互为C-2差向异构体。
61、<imgtitle="201703201490015841649022755.png"alt="22.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490015841649022755.png"/>
62、Sanger方法是利用氨基和______发生芳香亲核取代反应。
63、<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490019139088054095.png"title="201703201490019139088054095.png"alt="填图2.png"/>
64、完成下列反应<imgtitle="201703201490017291828059629.png"alt="231.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490017291828059629.png"width="506"height="73"style="width:506px;height:73px;"/>
65、D-葡萄糖与D-甘露糖可通过_____转变为D-果糖。
66、<imgtitle="201703201490014682117004849.png"alt="24.png"src="/resourcefile/uploadFiles/file/questionImgs/201703201490014682117004849.png"/>
67、为什么吡啶具有碱性？
68、以甲苯为原料，合成下列化合物：<imgsrc="/resourcefile/uploadFiles/file/questionImgs/201703201490014143143000768.png"title="201703201490014143143000768.png"alt="客观题5图片.png"width="118"height="90"style="width:118px;height:90px;"/>
69、试写出LiAlH4还原酯的机理。
70、三甲胺的分子量比二甲胺大，但其沸点比二甲胺低，这是为什么？
71、为什么氨基酸的熔点很高？
72、如何进行淀粉的鉴别？
73、简述硝基苯的结构特征。
74、什么是葡萄糖的变旋现象？
75、由指定的原料及不超过五个碳的有机原料和必要无机试剂合成下列化合物<imgsrc="data:image/png;base64,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"/>
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